粘土稳定剂的合成及性能评价.docxVIP

本科毕业设计（论文）题 目粘土稳定剂的合成及性能评价 学生姓名蒋纪恩学　号0909020131教学院系化学化工学院专业年级应用化学2009级指导教师韩利娟职　称副教授单　　位西南石油大学完成日期2013年6月15日Southwest Petroleum UniversityGraduation ThesisSynthesis and performance evaluation of clay stabilizerGrade: 2009Name: Jiang JienSpeciality: Applied ChemistryAdviser: Assoc Prof. Han LijuanSchool of Chemistry and Chemical Engineering2013 Chengdu, P.R.China摘要 油气层中普遍含有粘土矿物。油田开采作业使用的外界流体与油气层中含有的粘土矿物不配伍时，这些粘土矿物会发生水化膨胀与分散运移，从而堵塞油气通道，使油气层的渗透率降低，严重的时候甚至会堵死油气层。为了抑制和降低粘土矿物对油气层的损害，本文从提高粘土稳定剂的防膨性与长效性等出发，选用环氧氯丙烷和二甲胺共聚，并与乙二胺交联，合成了一种季铵盐型阳离子粘土稳定剂。并分别讨论了反应温度、反应时间、单体配比、引发剂加量及交联剂加量等聚合条件对产物防膨率的影响，得出了最佳的合成方案。聚合体系的反应时间t=6h、反应温度T=45℃、单体摩尔配比(环氧氯丙烷:二甲胺)为1:1.2、引发剂用量(相对于单体质量)0. 11%、交联剂(乙二胺)加量0. 5%。实验结果表明:最佳合成方案产物的加量为2%时，其防膨率可以达到88.6% 。根据中华人民共和国石油天然气行业标“SY/T5971-94，注水用粘土稳定剂性能评价方法”对产品进行了评价。结果表明该产物对粘土水化膨胀的抑制具有良好效果性;有较好的耐温性;产物与无机盐NH4C1的复配具有更好的防膨效果，大大的减少了聚合物的用量，从而减小了施工过程中聚合物残渣对储层造成的潜在伤害，所以具有很好的开发前景。关键词:粘土稳定剂；阳离子；聚合；季铵盐；性能评价AbstractClay minerals widely present in the oil-gas reservoir, when its not compatible between the external fluid and the clay minerals of oil-gas level at oil exploiting operation, these clay minerals will cause hydrating expansion and dispersing migration, so blocking the oil-gas channels and highly decreasing the permeability of oil-gas level, even tube block the oil-gas level. In order to reduce and inhibit the clay minerals on reservoir damage, according to improving the swelling prevention percentage and lasting energy efficiency of clay stabilizer, this paper synthesized a new kand of quartanary ammonium salt type cationic clay stabilizer by copolying epichlorohydrin, dimethylamine and ethylenediamine. Also discussed the affect of the polymerization conditions of temperature, time, monomer ratio、initiator dosage and crosslinker dosage on swelling prevention percentage of the copolymer,and found the optimal synthesis of program. The reaction time of Polymerization t=6h、the reaction temperature T=45℃、the mole ratio of monomer (epichlorohydrin: dimethylamine) was 1:1.2