高固份飞机蒙皮涂料研制.docVIP

Shanghai Jiao Tong University STUDY ON HIGH-SOLID AIRCRAFT DOPE (A dissertation submitted for Master’s Degree) Student ：YanLi  Tutor Tutor  ：WangXiLing ：YuJianFeng  Specialty：Chemical Engineering School of Chemistry and Chemical Engineering Shanghai Jiaotong University January 201 摘要 本文以高固体份飞机蒙皮涂料为研究对象，首先制备了高固含量 低粘度的聚酯树脂，通过性能检测和表征研究所用单体及合成条件对 聚酯树脂性能的影响；研究了酸值大小和反应时间对其性能的影响； 利用凝胶渗透色谱测试树脂的分子量及分子量分布，研究了合成工艺 对树脂粘度的影响，探索合理的聚酯树脂的生产工艺。 以合成聚酯树脂等原材料为基料，通过与异氰酸酯固化剂反应， 制备得到了聚酯聚氨酯高固份飞机蒙皮涂料。主要研究了不同异氰酸 酯固化剂、NCO/OH 当量比、催化剂的种类以及用量对漆膜性能的影 响；研究了不同种型号 TiO2 含量对涂料耐候性的影响；通过抗冲击 性和遮盖率试验确定了涂料的颜基比，探讨了溶剂及助剂对高固份飞 机蒙皮涂料的影响，确定了高固份飞机蒙皮涂料的组成和性能。 本文研制的高固份飞机蒙皮涂料完全满足波音材料规范 BMS10-72 户外用装饰涂料系统的技术要求，是一种性能优良的飞机 保护和装饰涂料，符合环保的发展趋势，是一种很有发展潜力的涂料 品种。  关键字：  高固份，聚酯树脂，飞机蒙皮涂料，波音材料规范 Abstract The research on the high solid aircraft dope was studied in this paper. A novel kind of low viscosity polyester resin was successfully synthesized. Effect of different monomers, acid value, and reaction time, molecular weight and molecular weight distribution on the properties of the polyester resin was investigated by the ways of FTIR, GPC. The synthesis process and the production processes were also researched herein. The different kinds of isocyanate prepolymer curing agent, NCO/OH ratio, the different kinds of TiO2 and pigment binder ratio content on the coating weather and additives on the performance of high-solid aircraft dope were probed. Finally, the formula of the high-solid-content aircraft dope was determined. This high solid content paint was synthesized to apply in Boeing material specification BMS10-72. The results showed the dope was an excellent aircraft protection and decorative coatings. It was an environmental friendly material, which was in consistent with the national policies of the environmental protection. Keywords: high solid content; polyester resin; aircraft coating; Boeing material specification 目录 目录 .........................................................................................