7A04铝合金在海洋大气环境中初期腐蚀的电化学特性 Electrochemical performance of initial corrosion of 7A04 aluminium alloy in marine atmosphere.pdfVIP
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第19卷第2期 中国有色金属学报 2009年2月
、,01.19No.2 TheChineseJournalofNonferrou$Metals Feb.2009
文章编号:1004-0609(2009)02—0346-07
7A04铝合金在海洋大气环境中初期腐蚀的电化学特性
董超芳,安英辉,李晓刚,生海,肖葵
(北京科技大学腐蚀与防护中心,北京100083)
摘要:通过盐雾腐蚀试验模拟研究7A04铝合金在海洋大气环境中的腐蚀初期规律,采用电化学交流阻抗测试
和扫描Kelvin探针技术,研究7A04铝合金在初期腐蚀过程中的电化学行为。结果表明:cl一对铝合金腐蚀有显著
的加速作用,盐雾试验初期表面出现点蚀坑;随盐雾时间增长,点蚀相互连接并扩展,电化学反应阻抗下降。扫
描开尔文探针测试结果表明:随腐蚀的不断进行,金属表面阴极区和阳极区不断发生变化,呈现局部腐蚀的特征,
表面电位也随时间逐渐升高,阴极区和阳极区逐渐变得明显,腐蚀反应处于不断加速过程。
关键词:7A04铝合金;大气腐蚀;电化学交流阻抗;扫描Kelvin探针
中图分类号:TG172.3 文献标识码: A
Electrochemicalofinitialcorrosionof
performance
aluminiuminmarine
7A04 alloy atmosphere
Kui
DONG Hai,XIAO
Chao-fang,ANYing-hui,LIXiao-gang,SHENG
andProtection ofScienceand 100083,china)
(Corrosion Center,UniversityTechnologyB喇ing,Beijing
Abstract:11圮initialcorrosionof7A04aluminiuminmarine wasstudied.Salttestwasusedto
alloy atmosphere fog
simulatethemarine environment.Electrochemical Kelvin
atmospheric impedancespectroscopy(EIS)andscanningprobe
to theelectrochemicalbehaviorof7A04aluminiuminmaline
(SHe、wereemployedinvestigate alloy atmosphere.The
resultsshowthattheCl—canacceleratethe corrosionof7A04alumininm the
atmospheric alloyduringbeginning
intheinitial ofsalt testandlinkeachotherto with testtime.
exposureperiod.PiRingsappear stage fog expandprolonging
Theelectrochemical declinesthecorrosiontest.TheSKPresultsindicatethattheano
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