纳米羟基磷灰石制备 范新健.pptVIP

纳米羟基磷灰石的制备 姓名：范 新 健 班级：10级应化一班;目 录;引言; 羟基磷灰石是组成人体骨骼和牙齿的重要组成部分，HAP是一种生物活性材料，具有良好的生物相容性、生物活性和生物稳定性，广泛应用于生物医药，催化和污水处理等领域。纳米羟基磷灰石在其功能上有一定的特性，如可以对一些肿瘤具有抑制作用,可以作为药物缓释材料抗生素、抗炎类等药物缓释载体，并且还可以作为某些化学反应的催化剂。;纳米HAP的制备方法主要有共沉淀法、水热法、溶胶-凝胶法、仿生合成和溶剂热法等。;由水热法合成均匀的不同纵横比和表面性质的F-替代HAP纳米管。少量3%F-加入HAP可以得到单晶纳米管。在合成单晶纳米管过程中加入PEG和油酸可以得到双亲性HAP纳米管。;合成方法;主要内容：;实验部分;Ca(NO3)2·4H2O;CaNO3·4H2O和KH2PO4为前驱体用溶胶-凝胶法合成六角形的纳米棒状羟基磷灰石。氨水调PH=9。HA凝胶在60oC烘干并在不同温度下煅烧300oC-700oC。得到直径为70-90nm，长为400-500nm的羟基磷灰石纳米棒。;实验部分;参考文献;[a] College of Materials Science and Technology, Beijing ForestryUniversity,Beijing 100083, P. R. China Fax: +86-10E-mail: mg_ma@bjfu.edu.cn [b] Department of Materials Chemistry, The ?ngstr?m Laboratory,Uppsala University,Uppsala 75121, Sweden Eur. J. Inorg. Chem. 0000, 0–0 Sol–gel synthesis and characterization of hydroxyapatite nanorodsSanosh Kunjalukkal Padmanabhana,b, Avinash Balakrishnana,b, Min-Cheol Chub, Yong Jin Leea, Taik Nam Kima, Seong-Jai Cho b,? a Department of Information and Electronic Materials Engineering, College of Engineering, Paichai University, Daejeon 302-735, Republic of Korea b Division of Metrology for Emerging Technology, Korea Research Institute of Standards and Science, 1 Doryong-Dong, Yuseong-Gu, Daejeon 305-340, Republic of Korea Particuology 7 (2009) 466–470 ;Preparation and characterization of hollow hydroxyapatite microspheres by spray drying methodRuixue Sun a, Yupeng Lu b,*, Kezheng Chen aa College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, Chinab School of Materials Science and Engineering, Shandong University, Jinan 250061, ChinaMaterials Science and Engineering C 29 (2009) 1088–1092AnEffectiveMorphologyControlofHydroxyapatiteCrystalsviaHydrothermalSynthesis Ine ′sS.Neira, YuryV.Kolen’ko, OlegI.Lebedev, GustaafVanTendeloo, HimadriS.Gupta,FranciscoGuitia ′n,and MasahiroYoshimuraCrysta