2A12铝合金表面铈盐掺杂硅烷杂化膜在3.5NaCl溶液中耐蚀性能的电化学研究.pdfVIP

44 11  Vol.44 No.11 2008 11 1372—1377 ACTA METALLURGICA SINICA Nov. 2008 pp.1372–1377 2A12 Æ 3.5%NaCl ∗ (, 213022) – , γ– (γ–GPTMS) (TEOS) , 2A12 (Ce(NO ) ) , . 3 3 (EIS), RE 3.5%NaCl () . , 13 , RE . , , , , TG174.36 A 0412−1961(2008)11−1372−06 ELECTROCHEMICAL STUDY OF CORROSION RESIS- TANCE OF CERIUM NITRATE DOPED SILANE–BASED HYBRID FILMS ON ALUMINUM ALLOY 2A12 ZHANG Jintao, YANG Chunyong, PAN Liang, LI Chundong Department of Chemical Engineering, Changzhou Institute of Technology, Changzhou 213022 Correspondent: ZHANG Jintao, associate professor, Tel: (0519 E-mail: zhangjt@czu.cn Supported by Natural Science Research Project, Education Department of Jiangsu Province (No.YW06005) and Science Research Program of Changzhou Insitute of Technology Manuscript received 2008–04–10, in revised form 2008–08–25 ABSTRACT Silane–based organic–inorganic hybrid films doped with cerium nitrate were prepared on 2A12 aluminum alloys by sol–gel method using γ–glycidoxypropyltrimethoxysilane (γ–GPTMS) and tetraethylorthosilicate (TEOS) precursors. The preparing conditions including doping concentration of cerium salt and curing temperature of coatings were investigated. The corrosion resistance of Ce–doped silane–based hybrid coatings was compared with non–doped silane–based hybrid films, chromate and RE conversion coatings for 2A12 aluminum alloys in 3.5%NaCl (mass fraction) solution by polarization curve and electrochemical impedance spectroscopy (EIS), respectively. The results indicated that the polarization resistance value of Ce–doped silane–based hybrid films increased