RE对热浸镀铝镀层组织及耐腐蚀性能影响.pdfVIP

第 23 卷 第 6 期 中 国 表 面 工 程 Vol.23 No.6 2010 年 12 月 CHINA SURFACE ENGINEERING December 2010 50 中 国 表 面 工 程 2010 年 doi: 10.3969/j.issn.1007−9289.2010.06.005 RE 对热浸镀铝镀层组织及耐腐蚀性能的影响 孙 伟，蔡启舟，罗 强 （华中科技大学材料成型及模具技术国家重点实验室，武汉 430074 ） 摘 要：研究了混合稀土（RE ）对 45 钢热浸镀铝镀层微观组织和耐蚀性能的影响。结果表明，45 钢热浸镀铝镀层由 外层的 Al 层和内层的过渡层组成，过渡层与基体呈锯齿状冶金结合。当 RE 加入量不超过 0.5 %时，随 RE 加入量增 加 Al 层厚度逐渐减小，当 RE 加入量超过 0.5 %后 Al 层厚度又增加。过渡层厚度则先增加（0.0 %～0.1 % RE）后逐 渐降低。RE 能细化热浸镀铝层中 FeAl3 相。动电位极化曲线测试及耐蚀性试验表明，RE 加入量 0.5 %的热浸镀试样耐 蚀性效果最好，耐盐水腐蚀失重试验中其耐蚀性约为 45 钢基底的 4 倍，热浸镀纯铝的 2 倍。 关键词：稀土；热浸镀铝；微观组织；耐蚀性 中图分类号：TG 174.443 文献标识码：A 文章编号：1007–9289(2010)06–0024–06 Effects of Rare Earth on Microstructure and Corrosion Resistance of Hot–dip Aluminum Coating SUN Wei, CAI Qi−zhou, LUO Qiang (State Key Laboratory of Material Processing and Die Mould Technology, Huazhong University of Science and Technology, Wuhan 430074) Abstract: The effects of rare earth on microstructure and corrosion resistance of hot−dip aluminum coating were studied. The results show that a two−layer coating is formed, consisted of an external Al layer with Al and FeAl3 as well as an interlayer with Fe Al and FeAl , interlayer and the substrate take the shape of jagged metallurgical bonding. The Al layer becomes 2 5 3 thinner with increasing the rare earth content from 0.0 %～0.5 %, then it gets thicker when the RE content exceeds 0.5 %. But the thickness of interlayer begins obviously increased when the content of 0.1 % RE is added, then it gets thinner gradually when the content of RE is more than 0.1 %. It is also found that FeAl3 phase formed i