低品位氧化锌矿在MACA体系中循环浸出.pdfVIP

第 21 卷第 1 期 中国有色金属学报 2011 年 1 月 Vol.21 No.1 The Chinese Journal of Nonferrous Metals Jan. 2011 文章编号：1004-0609(2011)01-0214-06 低品位氧化锌矿在 MACA 体系中的循环浸出 唐谟堂, 张家靓, 王 博, 杨声海, 何 静, 唐朝波, 杨建广 ( 中南大学 冶金科学与工程学院，长沙 410083) 摘 要：研究Me( Ⅱ)-NH Cl-NH -H O(MACA)体系处理兰坪低品位氧化锌矿的浸出过程，提出用循环浸出方法富 4 3 2 集浸出液中锌浓度的工艺技术方案。结果表明：循环浸出的优化条件为液固比 4:1 、常温、搅拌速度 300 r/min、 浸出时间 3 h ；通过循环次数分别为 14、15 及 10 的 3 个阶段的循环浸出试验，获得渣计锌浸出率≥69%、浸出液 锌浓度≥33 g/L 的较好结果。该工艺具有流程简短、能耗低、净化容易、环境友好等优点，对低品位高碱性脉石 难选氧化锌矿的开发利用具有重要意义。 关键词：锌冶金； 低品位氧化锌矿； MACA 体系； 循环浸出 中图分类号：TF813 文献标志码：A Cycle leaching of low grade zinc oxide ores in MACA system TANG Mo-tang, ZHANG Jia-liang, WANG Bo, YANG Sheng-hai, HE Jing, TANG Chao-bo, YANG Jian-guang (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The leaching processes of the low grade zinc oxide ores from Lanping in the system of Me( Ⅱ)-NH Cl-NH -H O(MACA) were studied. The technical process of enriching the concentration of zinc in lixivium 4 3 2 by cycle leaching was proposed. The results show that the optimal conditions are found, including the ratio of liquid to solid to be 4, stirring speed to be 300 r/min, leaching time to be 3 h and at ambient temperature. Three-stage experiments of cycle leaching were carried out, and the results indicated that the zinc-leaching rate is more than 69% and the zinc concentration of leaching solution is more than 33 g/L. This process has lots of advantages, including a simple flow sheet, low energy consumption, easy purification, being environment-friendly and so o