机械活化木薯淀粉羧甲基化产物的结构表征.pdfVIP

74 2010, Vol. 31, No. 13 食品科学 ※基础研究 谭义秋 (广西民族师范学院化学与生物工程系，广西 崇左 532200) 采用搅拌球磨机对木薯淀粉进行机械活化，以活化 60min 的木薯淀粉为原料，氢氧化钠为催化剂，一氯 乙酸为醚化剂干法合成羧甲基淀粉，利用红外光谱、扫描电子显微镜、X 射线衍射等手段对产物的结构进行表征 分析，并与原木薯淀粉合成的羧甲基淀粉进行比较。结果表明：机械活化对木薯羧甲基淀粉的结构有显著影响； 原木薯淀粉的羧甲基化反应受表面控制，主要发生在无定形区，部分发生在结晶区，产物含有结晶结构并保留着 淀粉的颗粒形态；活化淀粉的羧甲基化反应在淀粉团粒表面及内部均匀进行，产物呈无规则黏连形态，是无定形 的聚集状态结构。 ：机械活化；木薯羧甲基淀粉；结构表征 Structural Characterization of Carboxymethylated Cassava Starch Prepared Based on Mechanical Activation TAN Yi-qiu (Department of Chemistry and Biology Engineering, Guangxi Normal University for Nationalities, Chongzuo 532200, China) Abstract：Cassava starch was mechanically activated for 60 min using a stirring type ball mill in order to provide activated cassava starch for preparing carboxymethylated starch using NaOH as a catalyst and ClCH2COOH as an etherification agent. The structure of carboxymethylated cassava starch was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD). After mechanical activation, the structure of cassava starch had no obvious changes. Carboxymethylation reaction could be observed on the surface and interior of activated cassava starch. Its carboxymethylated counterpart showed an irregular adhesive form and an aggregative state and maintained both the pre- carboxymethylation crystal structure and morphological features of starch granules. In contrast, carboxymethylation controlled on the surface area was mainly completed in the amorphous zone and partly in the crystalline area of inactivated cassava starch. Key words ：mechanical activation ；carboxymethylated cassava starch ；structural characterization 中图分类号：TS236.9 文献标识码：A