PFS 法处理镍钼矿酸浸液萃钼余液研究.docVIP

PFS法处理镍钼矿酸浸液萃钼余液的研究 胡磊1,2，梁新星3，郭持皓1，肖连生2，曾之琪2 （1.北京矿冶研究总院，北京 100160；2.中南大学 冶金科学与工程学院，长沙 4100833.万宝矿产有限公司，北京 100053） 摘要：采用聚合硫酸铁法处理镍钼矿酸浸液萃钼余液中的重金属离子和化学耗氧量（COD）双氧水用量、用量、搅拌时间、pH对余液中Zn2+、Pb2+Ni2+及COD含量的影响。结果表明双氧水用量20 mLL、用量60 mgL、搅拌时间90 min、pH 11.0，COD可降至500 mgL以下，去除率高达89%，重金属离子均达到GB 8978-1996污水综合排放一级标准。 关键词：萃钼余液；聚合硫酸铁；双氧水；重金属离子中图分类号：X703.1 文献标志码：A 文章编号：1007-7545（2014）10-0000-00 Study o Treatment of Molybdenum Extraction Raffinate from Acidic Leaching Solution of Ni-Mo Ores by Polyferric Sulfate (PFS) HU Lei1,2, LIANG Xin-xing3, GUO Chi-hao1, XIAO Lian-sheng2, ZENG Zhi-qi2 （1. Beijing General Research Institute of Mining and Metallurgy, Beijing 100160, China; 2. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 3. Wanbao Mining Co. Ltd., Beijing 100053, China） Abstract: eavy metal ions and chemical oxygen demand (COD) in molybdenum extraction raffinate from acidic leaching solution of Ni-Mo ores were treated by polyferric sulfate (PFS). The effects of dosage of hydrogen peroxide and PFS, stirring time and pH value on concentration of Zn2+, Pb2+, Ni2+ and COD in raffinate were investigated. The results show that COD concentration can be reduced to 500 mg/L below with removal rate of 89%, and heavy metal ions meet the integrated wastewater discharge standard of GB 8978-1996 under the optimum conditions including dosage of hydrogen peroxide of 20 mL/L, PFS dosage of 60 mg/L, stirring time of 90 min and pH value of 11.0. Key words: molybdenum extraction raffinate; polyferric sulfate; hydrogen peroxide; heavy metal ions 镍钼矿作为我国一种特有的多金属复杂矿[1-5]。近年来，随着富矿资源的不断开采，高品位镍钼矿日益匮乏，已远不能满足当前需求，因而从低品位镍钼矿中回收镍钼已备受关注和重视[6-10]。目前，镍钼矿的矿物分解可分为酸法和碱法两类。为从分解液中富集回收钼，常采用溶剂萃取或离子交换工艺[1]。其中，溶剂萃取法与离子交换法相比，潜在的优点是易于实现连续生产回收率高废水排放量少适用性广。但萃钼过程中产生的余液不能直接排放本以镍钼矿酸浸液的萃钼余液为研究对象，采用聚合硫酸铁（PFS）法处理，获得了良好的效果。 1 试验 1.1试验料液 试验原料液是镍钼矿酸浸液萃钼余液，外观为浑浊、黄色，pH4.1。试验料液成分mg/L）：Zn2+ 27.90、Pb2+ 0.801、Ni2+ 2.60、COD 4 479。 1.2 试验仪器与试剂 主要仪器：pH计、S312型电动搅拌器、GG-17型真空抽滤设备、容量瓶、移液管、烧杯、玻璃棒、量