电化学传感器论文：电化学传感器 甲基对硫磷 介孔二氧化硅 L-赖氨酸 5-氨基-2-巯基-1,3,4-噻二唑.docVIP

【关键词】电化学传感器 甲基对硫磷 介孔二氧化硅 L-赖氨酸 5-氨基-2-巯基-1,3,4-噻二唑 【英文关键词】electroanalysis Methyl-parathion Mesoporous silica oxide L-lysine 5-amino-2-mercapto-1,3,4-thiadiazde 电化学传感器论文：甲基对硫磷电化学传感器的研究 【中文摘要】化学修饰电极是目前电分析化学中最活跃的一个研究领域。其特色在于能在基体电极表面进行分子设计，使电极达到预定功能，从而有望成为集富集、分离和选择性于一体的新型检测体系，这种方法在电化学和电分析化学显现出诱人的发展前景。基于此，我们构建了几种新型甲基对硫磷电化学传感器，主要研究工作如下：1、本文以十六烷基三甲基溴化铵（CTAB）为模板，在NaOH形成的碱性氛围下合成出了介孔二氧化硅纳米材料。并基于介孔二氧化硅纳米材料制成修饰碳糊电极，以K3为探针，考察了介孔二氧化硅纳米材料修饰碳糊电极的电化学性质，发现其氧化- 【英文摘要】Chemically modified electrode is an active research area in electroanalytical chemistry. The attractive characteristic of the modified electrode is that its function can be achieved by modified the electrode surface at molecular level.The modification makes the electrode possess many functions such as enrichment, separation and selectivity for the determination. Thus, chemically modified electrode attracted much attention and possesses attractive prospects in analytical chemistry. In this work, we developed several electrochemical sensors for parathion-methyl. The main contents of this work were proposed as following:1. Mesoporous silica (Meso-SiO2) was synthesized using cetyltrimethylammonium bromide (CTAB) as the template under alkaline atmosphere. After that, a mesoporous SiO2-modified carbon paste electrode was fabricated, the electrochemical properties of the modified electrode were characterized using K3[Fe(CN)6] as electrochemical probes. Compared to the unmodified electrode, it was found that the redox peak current of K3[Fe(CN)6] was significantly enhanced at the modified electrode. Electrochemical behaviors of methyl-parathion at the modified electrodes were investigated by cyclic voltammetry and square wave voltammetry. The results indicate that the modified electrode can improve the current response of methyl parathion. The effects of the electrolyte, preconcentration time, accumulation potential, pH value, mesoporous silica dosage, scanning rate and other conditions on the oxidation pea