13C固体核磁共振分析煤中含氧官能团的研究.pdfVIP

第41卷 第12期 燃摇 料摇 化摇 学摇 学摇 报 Vol.41No.12 2013年12月 Journal of Fuel Chemistry and Technology Dec. 2013 文章编号:0253鄄2409(2013)12鄄1422鄄05 13 C 固体核磁共振分析煤中含氧官能团的研究 王永刚,周剑林,陈艳巨,胡秀秀,张摇 书,林雄超 (中国矿业大学 化学与环境工程学院,北京 摇 100083) 13 13 摘摇 要:采用 C交叉极化/ 魔角旋转鄄核磁共振( C CP/ MASNMR)技术对四种煤进行分析,结合化学分析方法,考察了含 13 氧官能团的分布规律,尤其是非活性醚键的含量。 结果表明, C CP/ MAS NMR方法可以定量分析煤中部分含氧官能团,四 13 种煤中羧基和羰基的含量分别为0.00~1.41和0.45~1.91mol/ kg; C CP/ MAS NMR与化学分析方法结合,可以定量解析 煤中非活性醚键的含量,四种煤的醚键含量值为5.33~10.54mol/ kg,而活性醚键含量仅为0.04 ~0.13mol/ kg,煤中醚键的 赋存状态以非活性醚键为主。 13 关键词:煤;含氧官能团; C鄄CP/ MASNMR;非活性醚键 中图分类号:TQ533.9摇 摇 文献标识码:A 13 Contents of O鄄containing functional groups in coals by C NMR analysis WANG Yong鄄gang,ZHOU Jian鄄lin,CHEN Yan鄄ju,HU Xiu鄄xiu,ZHANG Shu,LIN Xiong鄄chao (School of Chemical and EnvironmentalEngineering, China University of Mining and Technology,Beijing摇 100083,China) 13 Abstract:The solid statehighresolution CCP/ MASNMRtechnology wasemployedtoanalyze O鄄containing functional groupsin4 coals. The variation and contents of inactive O鄄containing functional groups in the coals 13 were obtained in combination with chemical method. The results show that the C CP/ MAS NMR method is effective toobtainthecontentsof someO鄄containingfunctionalgroups. Thecontentsofcarboxylandcarbonylin the low rank coal are from0.00 to 1.41and f