石油磺酸盐对原油界面性质及其乳状液稳定性的影响.pdfVIP

维普资讯 ChineseJ．Chem．Eng．，13(5)691—695(2005) RESEARCH NoTES EffectofPetroleum Sulphonateon InterfacialProperty and StabilityofCrudeoilEmulsions WANGHuiyun(~慧云)，LIMingyuan(李明远) ，wuZhaoliang(吴肇亮)and LINMeiqin(林梅钦) StateKeyLaboratoryofHeavyOilProcessing，EOR ResearchCenterofChinaUniversityofPetroleum Beijing Beijing102249，China Abstract Theinfluenceofpetroleum sulphonatefTRS)oninterfacialpropertiesandstabilityoftheemulsions formedbyofrmationwaterandasphaltene．resinandcrudemodeloilsfrom Gudongcrudeoilwasinvestigated bymeasurementofinterfacialshearviscosity,interfacialtension(IFT1andemulsionstability．Withincreasing petroleum sulphonateconcentration，IFT betweentheformationwaterandtheasphaltene，resinandcrudemodel oilsdecreasessignificantly．Theinterfacialshearviscosityandemulsion stability ofasphalteneandcrudemodeloil system increaseforthepetroleum sulphonateconcentrationintherange0．1％to0．3％．anddecreaseslightlywhen theconcentrationofthesurfactantis0．5％．Thereexistsaclosecorrelationbetweentheinterfacialshearviscosity and the stability oftheem ulsionsofrmedbyasphalteneorcrudemodeloilsandpetroleum sulphonatesolution． Thestabilityoftheemulsionsisdeterminedbythestrengthoftheinterfacialfilm ofrmedofpetroleum sulphonate moleculesandthenaturalinterfacialactivecomponentsintheasphaltenefractionandthecrudeoil．Theasphaltene inthecrudeoilplaysamajorroleindeterminingtheinterfacialpropertiesandthestabilityoftheemulsions． Keywords asphaltene，petroleumsulphonate(WaS)，interfacialtension，interfacialshearviscosity，emulsionsta- bility 1 INTRoDUCTIoN waterandthestabilityofcrudeoilemulsion hasnot Inoilfieldsbothwater-in-crudeoilfw／o1and beenunderstoodclearly． crudeoil—in-waterfo／w1em