水热电泳沉积法制备硅酸钇涂层25737.pdfVIP

31 20 武 汉 理 工 大 学 学 报 Vol.31 No.20 2009 10 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY Oct. 2009 DOI: 10.3963/j.issn. 1671-4431.2009.20.004 刘 淼, 黄剑锋, 曹丽云, 张玉涛, 邓 飞, 吴建鹏 (, 710021) : 以声化学法合成的纳米硅酸钇粉体为原料, 异丙醇为溶剂, 碘为荷电介质,采用水 电泳沉积方法在SiC-C/ C 复合材料表面制备硅酸钇涂层借助X D 和SEM 对涂层的晶相组成表面和断面的微结构形貌进行表征重点研究 了水 电泳沉积温度对涂层结构及抗氧化性能的影响结果表明涂层中以Y Si O 为主晶相, 涂层的厚度和致密性随 2 2 7 着水 温度的增加而提高与包埋法制备的SiC 涂层相比, 水 电泳沉积制备的硅酸钇复相涂层具有更好的抗氧化性 - 3 3 能涂层试样在 1 500 e 的空气气氛下氧化35 h 后失重为0. 32@ 10 g/ cm : 碳/碳复合材料; 硅酸钇; 水 电泳沉积 : TB 332 : A : 1671-4431(2009)20-0011-04 Yttrium Silicates Coatings repared by a Hydrothermal Electrophoresis Deposition rocess LI U M iao , H UA N G J ian-f eng , CA O L i-y un , ZH A N G Yu-tao, D EN G Fei , W U Jian-p eng ( School of Materials Science and Engineering, Shanxi University of Science and Technology, Xi. an 710021, China) Abstract: Yttrium silicates coatings are deposited on SiC-C/ C composites surface by a hydrothermal electrophoresis deposi- tion process using yttrium silicates nano-crystallites, isopropanol and iodine as source materials, solvent and charging agent re- spectively. The yttrium silicates nano-crystallites are pre-prepared by a sonochemical process. Phase compositions, surface and cross-section microstructures of the as-prepared mult-i coatings are characterized by X D and SEM. The influences of deposition temperatures on the microstructures and oxidation resistance of the yttrium silic