Mn-Cu耐候钢锈层离子选择特性与结构关系研究.pdfVIP

Mn-Cu 耐候钢锈层离子选择特性与结构关系的研究 俊华 柯伟 （中国科学院金属研究所，沈阳，110016） 摘要：应用X 射线吸收精细结构谱（EXAFS ）方法分析了采用循环干湿交替模拟腐蚀加速实验制备的Mn-Cu 耐候钢锈层以描述锈层组分中Mn、Cu 元素周边的局部结构。样品的EXAFS 谱由合肥国家同步辐射实验室电 子加速装置获得。采用Fourier 变换分离出Mn、Cu 原子的第一配位层的数据，对该单层 据进行反Fourier 变 换后用Fe O 模型进行曲线拟合。结果表明，Cu 在锈层中与4 个O2-配位，说明其存在于反尖晶石结构的正四 3 4 面体间隙中；Mn 与6 个O2-配位，说明其存在于反尖晶石结构的正八面体间隙中。Mn-Cu 耐候钢锈层的阳离子 + 2- - 选择性特征可以解释为锈层的Fe O 组分中，Cu 与O 配位造成Fe O 颗粒局部负电荷过剩，它排斥Cl 向金属 3 4 3 4 表面迁移。 关键词：EXAFS 谱；Mn-Cu 耐候钢；阳离子选择性；局部结构 A Fundamental Study on Developing Cost-effective Mn-Cu-P Alloy Weathering Steel DONG Jun-hua , KE Wei (State Key Laboratory of Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, 62 Wencui Road, Shenyang 110016, China) Abstract: The performance of a series of Mn-Cu-P alloying steels resisting atmospheric corrosion has been investigated by applying the alternate wet/dry corrosion accelerating test simulating to both coastal and industrial atmosphere. It showed that the binary addition of Mn-Cu can synergistically improve the corrosion performance of the weathering steel resisting to the coastal atmosphere, and the triplex addition of Mn-Cu-P can enhance the corrosion resistance of the weathering steel to the industrial - atmosphere (pH=4). Under the simulated coastal c