不同密度煤焦结构及燃烧动力学的研究.pdfVIP

中国科技论文在线 不同密度煤焦结构及燃烧动力学研究 李欢* （中国矿业大学化工学院，江苏 徐州 221116） 摘要：用浮沉法从两种不同变质程度的煤粉中分选出低、中两个密度级别的组分，在 1450 5 ℃的滴管炉上制焦。用激光粒度仪对不同密度级煤焦进行粒度分析，用气体吸附仪测定煤焦 的比表面积和孔容，最后用TGA研究不同煤焦的反应活性，并进行了煤焦燃烧动力学参数的 求取。两种煤粉分选后所得的低密度组分的体积平均粒径均大于中密度组分。对于枣庄烟煤 焦，低密度组分的膨胀不如中密度组分明显；而龙岩无烟煤低密度组分的膨胀要优于中密度 组分。对焦样进行比表面积和孔隙结构测定发现，两种煤的低密度焦比表面积均大于中密度 10 焦。对比同种煤、不同密度级煤焦的燃烧反应活性发现：含内在矿物煤焦的整体反应活性明 显优于中密度焦。机理研究表明：内在矿物对煤焦的燃烧反应起催化作用。 关键词：煤焦结构；燃烧反应性；热解；矿物质 中图分类号：TK16 15 Study on the char structures and combustion dynamic parameters of fractions of pulverized coal Li Huan (School of Chemical Engineering，China University of Mining and Technology, JiangSu XuZhou 221116) 20 Abstract: Two fraction coals of low density and medium density were separated from each of the two pulverized coals with a float-sink procedure, and then charred in a drop tube furnace under 1450 ℃. Laser Particle Sizer was employed to observe the particle size and gas adsorption study was used to determine their surface area and pore volume. The chars were also subjected to TGA study for their combustion reactivity research and dynamic parameters calculation. The particle sizes of both ZZ and 25 LY indicate that the samples of low density are larger than that of medium density. It has been observed that the swelling ratio of ZZ increase with decreasing density. To the contrary, for sample LY, the swelling ratio decreases with increasing density. Results show that the surface area of the low density chars is higher than that of medium density chars for the two coals, and the reactivity