考察利用APTS对多壁碳纳米管进行该性后其对CO2吸附性能有所提高.pdfVIP

Science of the Total Environment 407 (2009) 3017–3023 Contents lists available at ScienceDirect Science of the Total Environment journal homepage: /locate/scitotenv Capture of CO2 from flue gas via multiwalled carbon nanotubes Fengsheng Su a, Chungsying Lu a,⁎, Wenfa Cnen a, Hsunling Bai b, Jyh Feng Hwang c a Department of Environmental Engineering, National Chung Hsing University, Taichung 402, Taiwan b Institute of Environmental Engineering, National Chiao Tung University, Hsinchu 300, Taiwan c Fuel Utilization Lab., Industrial Energy Conservation Technology Division, Energy and Environment Research Laboratories, Industrial Technology Research Institute, Hsinchu 310, Taiwan a r t i c l e i n f o a b s t r a c t Article history: Carbon nanotubes (CNTs) were modified by 3-aminopropyl-triethoxysilane (APTS) solution and were tested Received 30 August 2008 for its CO2 adsorption potential at multiple temperatures (20–100 °C). The physicochemical properties of Received in revised form 14 December 2008 CNTs were changed after the modification, which makes CNTs adsorb more CO2 gases. The adsorption Accepted 7 January 2009 capacities of CO2 via CNTs and CNTs(APTS) decreased with temperature indicating the exothermic nature of Available online 7 February 2009 adsorption process and increased with water content in air at 0–7%. The mechanism of CO2 adsorption on CNTs and CNTs(APTS) appears mainly attributable to physical force regardless of temperature change, which K