三相环流浆态反应器高固含下固含率径向分布.pdfVIP

三相环流浆态反应器高固含下固含率的径向分布 1 刘马林 王铁峰 王金福 （清华大学化学工程系绿色反应工程与工艺北京市重点实验室，北京，100084） 摘要：本文开发了采用电导率探头测量局部固含率的新方法。实验测量了三相环流反应器中（含 内构件）固含率的径向分布，呈中心低边壁高态势。实验结果表明：在高固含低表观气速下，固 含率分布的空间不均匀性显著，边壁增加明显。固含的不均匀性随着表观气速的减小而增加（气 含率的不均匀性则相反），随全床平均固含率的增大而增加，说明高固含时流型的分布需要考虑 表观气速和全床平均固含率双重因素。 关键字：浆态床；局部固含率；测量方法 The radial distribution of phase holdup in three phase slurry loop reactors under high solid concentrations Malin Liu, Tiefeng Wang, Jinfu Wang (Department of chemical engineering, Tsinghua University,100084,Beijing,China) Abstract: The investigation of solid holdup spatial distribution in three phase slurry reactors is important to their design and scale up. A new conductance measurement method for local solid holdup is proposed in this paper. The radial distributions of solid holdup under different conditions were achieved using this method, and some conclusions were drawn out: the liquid-solid phases can’t be seen as a pseudo homogenous; especially the slurry reactor was operated under low superficial gas velocity and high solid concentrations, because of the non-uniform radial distribution of the solid holdup (higher near the wall). The method developed in this paper for measuring the local solid holdup can be used to experimentally investigate the spatial distribution of solid holdup in the LS and GLS system farther. Keywords: slurry reactors, local solid holdup, measurement methods 引 言 气升式浆态环流反应器具有结构简单、无机械传动部件、易密封、造价低、容易实现工 业放大等优点，在石油化工，能源化工，生物化工领域均有广泛的应用[1] 。随着能源形势的 日趋紧张，环流反应器在煤液化、浆态床合成甲醇和一步法合成二甲醚等过程中的应用得到 广泛重视并取得了重要研究进展。在三相浆态反应器中，固体颗粒相一般作为催化剂存在， 因此反应器操作在高固含率条件下可以提高催化剂装填量，有利于提高反应转化率；另一方 面，固含率增加会导致液固拟均相的表观粘度增加，并且会导致固含率的不均匀分布，对反