Cu催化的单电子转移活性自由基聚合制备石墨烯聚N,N-二甲基丙烯酰胺复合体系.pdfVIP

DOI: 10.6023/cjoc201404052 研究论文 有机化学 Chinese Journal of Organic Chemistry ARTICLE Cu 催化的单电子转移活性自由基聚合制备石墨烯/聚N,N-二甲基 丙烯酰胺复合体系 王凇旸 郭冠南 杨 东 胡建华* (聚合物分子工程国家重点实验室 复旦大学高分子科学系 上海 200433) 摘要 以天然石墨为起始原料, 采用改进的 Hummer 方法, 通过强酸氧化水解和超声分散制备了氧化石墨烯, 然后通 过肼还原和重氮化反应得到含有羟基的石墨烯(G-OH), 再通过酯化反应在石墨烯表面上引入了 α-氯代羰基, 从而得到 了含有单电子转移活性自由基聚合(SET-LRP)引发基团的石墨烯(G-Cl). 最后, 在石墨烯表面原位引发 N,N-二甲基丙烯 酰胺(DMAA)单体的 SET-LRP 聚合, 得到了 G-PDMAA 复合材料, G-PDMAA 在常规的有机溶剂和水中具有良好的分 散性. 关键词 石墨烯; 氧化石墨烯; N,N-二甲基丙烯酰胺; 单电子转移活性自由基聚合(SET-LRP) Preparation of Graphene/Poly(N,N-dimethylacrylamide) Nanocomposite via Cu-Catalyzed Single-Electron Transfer Living Radical Polymerization Wang, Songyang Guo, Guannan Yang, Dong Hu, Jianhua* (State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science , Fudan University, Shanghai 200433) Abstract Exfoliated graphene oxide (GO) sheets were prepared from natural graphite by a modified Hummer’s method, which included oxidative hydrolysis under strong acidic conditions and ultrasonic dispersing. GO was firstly reduced by hy- drazine and then followed by a diazonium addition reaction to give graphene containing hydroxyls (G-OH), which was con- verted to graphene with singel eclectron transfer-living radical polymerization (SET-LRP) initiating groups via esterification with 2-chloropropionyl chloride. Finally, poly(N,N-dim