酸解破乳作用处理高含固率洗毛废水的研究.pdfVIP

第7卷 第5期 环境污染治理技术与设备 Vo1．7。No．5 2 0 0 6年 5月 Techniques and Equipment for Environmental Pollution Control May 2 0 0 6 酸解破乳作用处理高含固率洗毛废水的研究 何 锋 周立祥 王电站 (南京农业大学资源环境学院环境工程系，南京210095) 摘 要 洗毛废水是一种高浓度有机废水，含固率高，主要成分是羊毛脂、羧酸盐和土杂，由于强极性物质的存在和胶 体强的负电性，导致洗毛废水形成稳定的乳化体系。本试验通过加入硫酸改变洗毛废水的有机组成，降低体系的Zeta电 位，破坏体系的稳定性，从而使得有机物发生凝聚沉降，达到去除COD的目的。硫酸加入量达到0．2％或以上时对洗毛废 水中ss的自然沉降性、絮凝性和极性有很大影响，比阻从远大于9．81×10”m／ks，下降为5．54×10 m／kg，COD去除率达 到86．8％，SS去除率达到98％。因此，洗毛废水加酸处理后通过机械脱水，实现固液分离，以降低原废水的色度和大幅降 低COD的方式，是可供考虑的处理工艺。 关键词 酸解作用 破乳 洗毛废水 COD去除 中图分类号 X703 文献标识码 A 文章编号 1008．9241(2006)05-0100-04 Demulsification of woolscouring effluent with high organic solid content through acidic hydrOlyzatiOn He Feng Zhou Lixiang Wang Dianzhan (Department of Environmental Engineering，College of Resources and Environmental Sciences Nanjing Agricultural University，Nanjing 210095) Abstract Woolscouring effluent containing a great amount of lanolin，suint and dust is an organic wastewater with a high concentration of C OD and SS．In this study．sulfuric acid was added into woolscouring ef- fluent with an aim to reduce the polarity and Zeta potential of suspended organic colloid，resulting in organic colloid to agglomerate and sedimentate．It was showed that C OD and SS of woolscouring emuent could be re． moved easily by mechanical dewater procedure when the amount of H，SO d added to the wastewater was more than O．2％ and maintained in the system for 2 h at 60。C．Atier treated．woolscouring emuent had a good spontaneous sedimentation and dewaterability．as indicated by lower resistance rate of SS with 5．54×10 m／kg．The highest removal rates of C0D and SS are 86．8％ and nearly 100％．respectively． Key words acid hydrolyzation；demulsification；woolscouring effluent