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CommonIonEffectTheequilibriumexpressionincludes…:同离子效应平衡表现….ppt
Assume you have a saturated solution of calcium sulfate at a temperature of 25? C represented by the following equation: CaSO4 (s) ? Ca 2+ (aq) + SO4 2- (aq) If you add additional solid calcium sulfate to the saturated solution, what will happen? Nothing – Solid CaSO4 does not affect the equilibrium concentrations of Ca 2+ and SO4 2- If you allow a saturated solution of calcium sulfate to evaporate what will happen? Evaporation will reduce the volume of water and dissolved calcium sulfate must precipitate out since the concentrations of Ca 2+ and SO4 2- must remain constant for a system at equilibrium Assume you have a saturated solution of calcium sulfate at a temperature of 25? C represented by the following equation: CaSO4 (s) ? Ca 2+ (aq) + SO4 2- (aq) If you add additional solid potassium nitrate to the saturated solution, what will happen? Solid KNO3 will dissolve into K + and NO3 – but the equilibrium concentrations of Ca 2+ and SO4 2- will not change since K + and NO3 – are not part of the equilibrium Assume you have a saturated solution of calcium sulfate at a temperature of 25? C represented by the following equation: CaSO4 (s) ? Ca 2+ (aq) + SO4 2- (aq) If you add additional solid potassium sulfate to the saturated solution, what will happen? Solid K2SO4 will dissolve into K + and SO4 2- , tending to increase the concentration of SO4 2- . However, since the concentration SO4 2- cannot increase due to the equilibrium of Ca 2+ and SO42-, some dissolved Ca 2+ and SO42- must precipitate out as solid CaSO4 Common Ion EffectThe equilibrium expression includes the total concentration of an ion
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