Catalytic Decomposition of Chlorophenols Using Fiber-supported Cobalt Phthalocyanine.pdfVIP

402 JournalofDonghuaUniversity(Eng．Ed．)Vo1．26，No．4(2009) Catalytic Decomposition of ChlorophenolsUsing Fiber-supported CobaltPhthalOcyanine LOWang-yang(吕汪洋)，LINan(李 楠)，XUMin—hong(徐敏虹)，YAOYu一)，uan(姚玉元)“，CHEN Weln-xiIlg(陈文兴)。 2 KeyLaboratoryofAdvancedTextileMaterialsandManufacturingTechnology，MinistryofEducation，Z^ iangSci—TechUniversity， Hangzhou310018，C~ina 2 CollegeofTextiles，DonghuaUniversity，Shanghai201620，China Abstract．A novelheterogeneous catalyst， viscose fiber- To avoid further risks to the enviromn ent， some supportedocbaltphthaloeyanine(Co—TDTAPc—F)，was effectivemethodsfor the elimination ofCPshavebeen preparde byimmobilizingcobalttetra(2·4一dichloro—l，3， developed in rce entyears．The destructive tcehnologies 5一triazine)aminophthaloeyanine(Co一1 y1rAPc)onvisocse includephysicalchemsitrymethodssuch asadsorptionL ， fiberscovalently．Theoxidativeremovalofchlorophenols biologicaltreatments[ ，andadvancedoxidation processes such as 2 一 chlorophenoi， 4 一 chlorophenol， 2，4 一 (AOPs)一 ．Althoughadsorptionmethodsareeffectivefor dichlorophenol， and 2，4， 6 一 trichlomphenol was eliminating organic compounds， adosrbents easily get investigatde ni the acmlytic oxiadtive system ofC0 一 saturatde ， requiring regeneration or replacement． TDTAPc—F／H202．Furthermore。morethan98％ofthese Biologicaltreatmentsareoftenaffectedbythetoxicityof ehlorophenolsweredecomposde in4h．Phenol，oxalicacid， somesubstances，and the treatmenttmie isusually longer maleicacid，andsuccinicacid，etc．，weredetcetedbyhigh than thatrequired forothermethods~ ．Compared with performance Uqeid chromatography (HPLC) and ags adsorption andbiologicaltreatments，AOPs isprom~ing chromatography-massspectrophotometer (GC —MS)，and for the treatment of wastewater， containing organic theseshort-cha ni organic acidscould befurther oxid