2011_习题课2及总复习.pptVIP

来自相平衡(热力学)的启示 Questions for review (1): Mass Transfer in Multicomponent mixtures 1 (Around 10 points) Concepts: 1.1 Define or describe mass transfer processes, e.g., dialysis, gas separation, adsorption, membrane module, etc. 1.2 Describe or explain mass transfer phenomena or theories: Fick’s law, film theory. 2 (Around 30 points) How to set up a MS model for mass transfer: 2.1 Concerning the MS eqs.: units; velocity and flux forms; differential and difference forms; structured and non-structured. 2.2 Concerning the driving forces: multiple forces; ideality and thermodynamic model. Questions for review (2): Mass Transfer in Multicomponent mixtures 2.3 Concerning the friction forces: transport coefficients including diffusivity, friction coefficient and mass transfer coefficient; how many needed; interpolation formula; etc. 2.4 Concerning the bootstraps: 3 (Around 10 points) Derivation or proofing: Refer to the following slide. 4 (Around 20 points) Calculation of species velocity/flux: Dealing with not more than 3 components (including a possible solid matrix). . Maxwell Stefan: non-ideality in the driving force: example: Fick: non-ideality in the diffusivity: MS versus Fick thermodynamic correction factor Beginning or Ending ? 感谢同学们的配合和支持！ Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * Alternat 1 * * Mass Transfer in Multicomponent Mixtures （10:Final Exam Study Guide） Liu Hui State Key Lab of Chemical Resource Engineering, BUCT 2011 关于考试 开卷考试：11月17日，13:00~15:00，地点教321。带课本和计算器。 作业：下周四（11月10）前上传到公用信箱。 PART 1 Process Modeling: The Maxwell-Stefan Formulation 对象：不同的过程单元 ? 多组分蒸馏、萃取等， 透析和气体分离， 渗透蒸发（渗透汽化）和反渗透， 电解和电渗析， 离子交换和吸附， 多孔介质中的渗透和催化反应 对象：“膜” 上的多组分传质过程 Membrane Film 统一的模型化描述：力的平衡 驱动力（热力学）：源于组分的势梯度，包括浓度梯度（或更精确说是活度梯度），电场势梯度，压力梯度，离心场梯度及其它梯度。 摩擦力（动力学）：源于不同组分间的速度差。 MS formulation: the starting point the driving force on a species i in a mixture the sum of th