超吸水材料交联密度测定及对吸水性能的影响.pdfVIP

21 3 ( ) Vol. 21No. 3 2000 7 Journal of Huaqiao U niversity ( Natural Science) Jul. 2000 1000-5013(2000) 03-02 4-04 李国清　 林建明　 吴季怀 ( , 3 2011) , , = X 1 C X 1 K 1C+ K 2. , , . , , . , , 317. 3 : 34 T Q TB A , . , 13 , . , . ( 4 ) , . , , . , . 1 1. 1 5 Flory-Huggins , , Q5/ 3 = M c( 0. 5 - X 1) / D 2V 1, ( 1) , 2 , 1 Q D V ,X 1 ,M c .M c, ,M c. M c, Q , D 2 , V 1 1 , 1 . , 1 X X X . , : 1999-11-12( 19 5-) , , ; 3 : 2 5 , C, X 1 C X 1 = K 1C + K 2. ( 2) ( 2) ( 1) , D 2V 1QCH OH-H O5/ 3 = M c( 0. 5 - K 1C - K 2C) , 3 2 Y = QCH OH-H O5/ 3D 2V 1, K 2 0. 5, 3 2 c 1 Y = M ( 0. 5 - K C) . ( 3) ( 3) , Y C . C Y , , c . M 1. 2 , , . , ; , , . , c. M 2 2. 1 , , 4 . 2. 2 ( 1) D 2 . ( 2) , 1 V . ( 3) m ( 0. 1 g ) , 1. 0 L -. 24 h , , . QCH OH-H O = V / V 0, 3 2 , 0 ( 0 =