酸性助剂对催化剂及RFCC原料油裂化性能影响的研究.pdfVIP

10 2 Vol. 10 No. 2 2 0 0 2 3 INDUST RIAL CATALYSIS Mar . 2 0 0 2 RFCC 1 2 2 3 孙学文, 刘彦辉 , 樊桂臣, 高玉青 ( 1. ( ) 102249; 2. , 163511; 3. , 151400) : 本文考察了酸性助剂对催化剂及RFCC 裂化原料裂化性能汽油和柴油主要性质的影 响试验结果 明, RFCC 原料加入适量的酸性助剂后, 催化剂微反活性提高3~ 4 个单位, 轻 质油收率提高3% ~ 4% ( w t) , 产品分布得到改善, 所加入的酸性助剂不会进入产品中酸性 助剂用量最佳值在0. 25% ~ 0. 35% ( w t) 间, 其用量与所处理的原料和使用的催化剂有关同 时发现, 酸性助剂不仅适用于国产催化剂, 也适用于进口催化剂, 具有广泛的适用性 : 重油流化催化裂化; 酸性助剂; 碱性氮化物; 催化剂活性; 轻质油收率 + : TE624. 4 1 : A : 2002) Influence of acidic additives on cracking performance of RFCC catalyst and feed oil S UN X uewe n, LI U Yanhui, FA N Guichen, GA O Yuqi ng ( 1. The state ke Laborator of Heav Oil processing , U niversit of Petroleum Beijing , Beijing 102249, China; 2. Daqing Refiner Chemical Co. , Heilongjiang Daqing 163511 China; 3. Dept Petrochemical Engineering , Daqing Petroleum Institute, Heilongjiang Anda 151400, China) Abstract: In order to counteract against the decline in activit , selectivit of RFCC catal st and ield of light oil caused b existence of basic nitrogen compounds, Acidic additive is added to residue feedstock. simulating the condition of commercial, Comparison tests w ere made on a small catal tic cracking unit to investigate the effects of acidic additives on cracking performance of RFCC catal st and residue feedstock as w ell as properties of the gasoline and diesel products. Re sults from the tests show ed