广州市大气气态总汞含量季节和日变化特征.pdfVIP

中国环境科学 2012,32(9) ：1554~1558 China Environmental Science 广州市大气气态总汞含量季节和日变化特征 1,2 1 1 1 1 1 2 刘 明 ,陈来国 ,陶 俊 ,许振成 ,朱李华 ,钱冬林 ,范瑞芳 (1.环境保护部华南环境科学研究所,城市 环境研究中心,广东 广州 510655 ；2.华南师范大学生命科学学院,广东 广州 510631) 摘要：利用高时间分辨率自动测汞仪(tekran 2537B),于 2010-11~2011-11 对广州市大气气态总汞(TGM)进行了连续 1a 的观测.结果表明,广 州市大气气态总汞的年平均含量为(4.86±1.36)ng/m3,表明该地区受到了一定程度的大气汞污染.TGM 浓度按季节表现为:春季冬季秋季 夏季.TGM 污染呈现春高夏低的现象,气象因素如边界层、静止风是影响其季节分布不同的主要原因. 日变化趋势为中午最低,早晚出现 2 个高峰,边界层和温度对 TGM 日变化有很大影响.对广州市大气气态汞的可能来源分析结果表明,TGM 主要来源于本地人为排放,其中市内 燃煤电厂和水泥厂等人为源排放可能是广州市大气气态总汞的主要来源. 关键词：广州市；气态总汞；季节变化；日变化；来源 中图分类号：X131.1 文献标识码：A 文章编号：1000-6923(2012)09-1554-05 Seasonal and diurnal variation of total gaseous mercury in Guangzhou City. LIU Ming1,2, CHEN Lai-guo1*, TAO 1 1 1 1 2 Jun , XU Zhen-cheng , ZHU Li-hua , QIAN Dong-lin , FAN Rui-fang (1.Center for Research on Urban Environment, South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655, China； 2.College of Life Science, South China Normal University, Guangzhou 510631, China). China Environmental Science, 2012,32(9) ：1554~1558 Abstract ：Total gaseous mercury (TGM) was continuously monitored using high-resolution automatic atmospheric mercury vapor analyzer (Tekran 2537B) from November 2010 to November 2011 in Guangzhou. The annual average TGM concentration was (4.86±1.36)ng/m3, suggesting that the atmosphere was polluted by mercury in this area. The TGM level exhibited distinct seasonal variation by the following order: springwinterautumnsummer. TGM pollution was more serious in winter but less in summer, which was caused by meteorological factors such as boundary layer, static wind. The diurnal variation showed that t