锆铝复合层柱黏土固体超强酸的制备及催化性能.pdfVIP

· 1410 · 2007 35 10 Vol. 35 No. 10 2 0 0 7 1 0 JOURNAL OF THE CHINESE CERAMIC SOCIETY October 2007 ( 230009) SO42– X SO42– SO42– 200 g/L400500 SO42– 93.4% TQ016 A 0454–5648(2007)10–1410–05 PREPARATION AND CATALYTIC PERFORMANCE OF MIXED Zr/Al PILLARED CLAY SOLID SUPERACID YU ShaomingHAO Wenzheng WANG HualinLU Yaling ZHAI Linfeng SHI Tiejun (School of Chemical Engineering , Hefei University of Technology, Hefei 230009, China) Abstract: The methods of metal doping and sulfation modification on pillared clay were studied to promote its catalytic activity. Mixed Zr/Al cross-linked clay was prepared by cation exchange of Na-montmorillonite with mixed Zr/Al pillaring agent synthesized by substitution. Mixed Zr/Al pillared clay solid superacid catalyst was prepared from the cross-linked clay by sulfation on it. The catalyst was characterized by means of X-ray diffraction, Fourier transform infrared spectroscopy, NH3-temperature programmed desorption, specific surface area and pore diameter distribution measurement. Through experiments, the optimum sulfation conditions of mixed Zr/Al pillared clay were obtained. Using the esterification of acetic acid with n-butanol as a probe reaction, the catalyst ac- tivity was investigated. The results show that mixed Zr/Al pillaring agent was intercalated in between the layers of montmorillonite. The solid acidity of mixed Zr/Al pillared clay was increased after it was modified by SO42– and the clay became a solid superacid catalyst with a large specific surface area and u