超声波对棉织物活性染料染色的作用机制_赵海凤.pdfVIP

30 3 Vol. 30 No. 3 2009 3 Journal of Textile Research Mar. 2009 2009) 0300 205 赵海凤, 汪 澜, 林俊雄 ( , 310018) , , , , LS G , 2 : , ; 54 1% , 3715% ; 1 , 50% , 42% , ; ; ; ; :TS 1935 :A Mechanism of ultrasonic dyeing on cotton fabric with reactive dye ZHAO Haifeng, WANG Lan, LIN Junxiong ( Key Laboratory of Advanced Textile Materials and Manuf acturing Technology ( Zhej iang SciTech University) , Ministry of Education, Hangzhou, Zhejiang 310018, hina) Abstract The purposes of this research were to reduce dyeing temperature and dosages of dyestuffs and chemicals, and cut down the environmental pollution. Cotton fabric was dyed with a reactive dye, Cibacron Red LS G, under ultrasound condition or conventional condition. The influence of ultrasound on the dyeing mechanism of cotton fiber with reactive dye was analyzed through thermodynamic and kinetic studies. The results indicate that the ultrasound can not change the type of adsorption isotherm. It can increase the affinity of the dye on cotton fiber, decrease dyeing enthalpy by 54. 1% and dyeing entropy by 37. 15% respectively. The ultrasound can also enhance the diffusion constant by about one time and dyeing rate constant by over 50% , reduce dyeing activation energy by 42% , and shorten the halfdyeing time by about half. Key words cotton fabric; ultrasound; dyeing; thermodynamics; kinetics , 1 , 11 ( 1 tex 183 tex) [ 1- 4] LS G( K , , ) ; ( AR, ) , O( ) LS G LEO2100