重氮化反应 氨基变醛基 2-BROMO-4-METHYLBENZALDEHYDE.pdfVIP

Organic Syntheses, Coll. Vol. 5, p.139 (1973); Vol. 46, p.13 (1966). 2-BROMO-4-METHYLBENZALDEHYDE p [ -Tolualdehyde, 2-bromo-] Submitted by S. D. Jolad and S. Rajagopalan1. Checked by A. G. Szabo and Peter Yates. 1. Procedure A. Formaldoxime . A mixture of 11.5 g. (0.38 mole) of paraformaldehyde and 26.3 g. (0.38 mole) of hydroxylamine hydrochloride in 170 ml. of water is heated until a clear solution is obta