钛锆微球材料 重金属吸附.pdfVIP

www.afm-journal.de www.MaterialsV R E Facile Synthesis of Monodisperse Mesoporous Zirconium P A Titanium Oxide Microspheres with Varying Compositions P L and High Surface Areas for Heavy Metal Ion Sequestration L U F Dehong Chen, Lu Cao, Tracey L. Hanley, and Rachel A. Caruso* waste (radwaste) sequestration.[1–10] Monodisperse mesoporous zirconium titanium oxide microspheres with Recently the exploitation of these oxides varying compositions (Zr content from 0 to 100%), high surface areas (up to for heavy metal ion and radwaste seques- 2 tration has attracted attention because 413 m /g) and well-interconnected mesopores are synthesized via a com- of their demonstrated superior thermal, bined sol–gel self-assembly and solvothermal process. Surface areas, pore chemical, hydrolytic and radiolytic sta- diameters, crystallinity and mesostructures of the products are controlled by bilities, as well as outstanding durability changing the composition of the microspheres. The resulting mesoporous for long term service.[11–17] In contrast microspheres are tested as adsorbents to remove Cr (VI) anions from solution to the