基于LB膜技术制备的伏安传感器的研究与应用.pdfVIP

基于LB 膜技术制备的伏安传感器的研究与应用 邹丽娜 冶保献* 郑州大学化学系 E-mail: yebx@zzu.edu.cn LB膜(Langmuir-Blogett Film)技术是将气/液界面上紧密、有序排列的单分 子层以一定的方式转移到固体表面的成膜技术，并可以实现连续转移组装。所以 LB膜技术组装的膜具有膜厚超薄（单分子层）且厚度可控、膜中分子排列有序、 均匀性极好、且可根据需要进行分层组装等特点。将LB膜组装到常规伏安电极上， 就制作成了LB膜伏安传感器。近年来，我们课题组致力于LB膜伏安传感器的研究 与应用，先后制作了杯芳烃、聚苯胺和DNA LB膜修饰的玻碳电极伏安传感器，探 讨了不同修饰材料的LB膜制备过程，并分析了其制备过程中实验条件（亚相，成 膜材料用量等）对成膜性能的影响，制备出了三种不同性能的LB膜修饰电极。结 果表明，在最优实验参数下，相比较于裸玻碳电极，三种修饰电极对于被检测物 都有更好的响应信号,具有较好的选择性和稳定性。 Preparation and application of Langmuir-Blogett film voltammetric sensors Lina Zou, Baoxian Ye* Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, P R China Abstract: Langmuir-Blogett technique is transferring monolayer film in gas - liquid interface on the surface of solid and assembled continuous transferring. The LB film attracts more and more attention because of its ultrathin film, controllable thickness, regular molecular arrangement and excellent uniformity. It can be assembled layer by layer as required. This paper introduced preparation and application of calixarene, polyanion and DNA Langmuir-Blogett film modified electrode. The effects of subphase, content of material and other experimental factors on preparation were discussed in detail. The results show that，under certain experimental conditions ， compared to bare electrode, LB film modified electrode present high sensitivity, selectivity and good stability. 基于LB膜技术制备的伏安传感器的研究与应用 作者： 邹丽娜， 冶保献 作者单位： 郑州大学化学系 引用本文格式：邹丽娜.冶保献 基于LB膜技术制备的伏安传感器的研究与应用[会议论文] 2011