二次生长中间相炭微球的粒度分析和结构研究_李太平.pdfVIP

15 3 V o l15 N o3 2 0 0 7 6 MATER IA LS SC IENCE TECHNOLOGY Jun. , 2007 李太平, 王成扬, 李同起, 王 慧 ( , 300072 : 为研究添加中间相炭微球( M CM B 生球的煤焦油沥青中炭质中间相的发展情况, 实验中以热缩具 方法 420 下反应 12h得到二次生长的M CM B. 对比发现, M CM B 的收率较未添加条件下制得的球体有了 大幅度的提高. 在光学显微镜下观察二次生长后的中间相沥青, 发现M CM B 的生长具有双向性, 即分别向两 个尺寸(大球和小球 发展, 且随着M CM B 加入量的增加, 中间相沥青中大球的比例明显提高. 粒度分析和扫 描电子显微镜 ( SEM 对M CM B 的形貌表征结果也印证了这 一结论. 同时, SEM 下的微观表征还显示大球和 小球具有相同的断面结构特征. : 中间相炭微球(M CM B ; 形貌; 粒度分析; 结构; 二次生长 : TQ 12112 : A : 1005- 0299 ( 2007 03- 042 1- 04 Study on the granu larity and structure of secondary M CM B L I T a-i ping, WANG Cheng-yang, L I T ong-qi, WANG H ui ( K ey Labo ra tory for G reen Chem ica l T echno logy o f S tate Education M in istry, Schoo l o f Chem ica l Eng ineering and T echno logy, T ianj in U niv ers ity, T ianj in 300072, China Abs tract: In order to investigate the developm en t of carbonaceou sm esophase in coal tar pitch m od if ied by m e- socarbon m icrobeads ( M CM B , secondaryM CMB w ere prepared from a qu inoline- inso lubles con taining coa l tar p itch at 420 fo r 12 h. By com paring the MCM B prepared w ith the addition o fM CM B w ith those w ithou t M CMB addit ion, it has been found that the y ields o f secondary MCMB mi proved greatly. Under po larized ligh t m icroscope, the m esophase pitches w ith MCM B addition show s the phenom enon of tw o- size, .i e. the MCM B grow in two k inds o f sizes. The proportion of large spheres increases obv iou sly w ith the increm ent o f the a- m ount of m esocarbon m icrobeads add itive. T he results of granu larity analysis and scann ing electron m icroscopy