可见光响应半导体催化剂_综述.pdfVIP

第 18 卷 第 9 期 化　学　进　展 Vol. 18 No. 9 2006 年 9 月 PROGRESS IN CHEMISTRY 　Sep. , 2006 设计新型可见光响应的半导体光催化剂 龙明策　蔡　俊　蔡伟民 　陈　恒　柴歆烨 (上海交通大学环境科学与工程学院 　上海 200240) 摘 　要 　利用太阳能光解水制氢和降解有机污染物对解决能源和环境问题具有重要意义 ,而可见光响 应催化剂的研制是实现太阳光高效利用的关键。本文从可见光响应光催化剂的设计思路出发 ,从电子能带 结构、固溶体结构和微观复合结构三方面介绍了目前光催化剂的研究进展和发展方向。 关键词 　可见光 　半导体 　光催化剂 　光解水 　有机污染物 ( ) 中图分类号: O64332 ; O6441 ;TN30491 　文献标识码 : A 　文章编号 : 1005281X 2006 Design of Novel Visible Light Responding Semiconductor Photocatalysts Long Mingce 　Cai Jun 　Cai Weimin 　Chen Heng 　Chai Xinye ( School of Environmental Science and Engineering , Shanghai Jiaotong University , Shanghai 200240 , China) Abstract 　Water splitting for hydrogen evolving and organic pollutants degradation by utilization of solar energy have vital significance for solving the energy crisis and environmental problems. Developing visible light responding photocatalysts is the key for sunlight efficiently utilization. In this paper , based on the material designing ideas for visible light responding photocatalysts , recent progress is reviewed from three aspects : the electronic band structure , solid solution and microheterojunction structure. The developing orientation for further research is presented. Key words 　visible light ; semiconductor ; photocatalysts ; water splitting ; organic pollutants TiO2 [3 ] 、NaTaO3 [4 ] 等 ,仅在紫外光范围有响应 , 而波 1 　引言 长在 400nm 以下的紫外