固体酸催化剂反应精馏法合成乙酸正丙酯的研究.pdfVIP

37 8 V o.l 37 N o. 8 2008 8 A pplied Chem ica l Indu stry A ug. 2008 1 2 1 1 1 周广帅 , 向丹波, 诸林 , 樊力 , 谢长宇 1. , 6 10500; 2. , 6 10500 ) : , , , , 1 2, 1 2, 5 1. 49% : ; ; ; ; : TQ 028. 1 : A : 167 1- 3206 2008) 08- 0 896- 03 Study on synthesis ofN propyl acetate by reactive distillation m ethod w ith solid acid as catalyst 1 2 1 1 1 ZH O U Guang shua i , X IANG D anbo , ZH U L in , FAN L i , X I E Chang yu 1. G raduate Student Departm ent, Sou thw est P etro leum U niversity, Chengdu 610500, China; 2. S ichuan T ianhua L mi ited L iab ility Com pany, Chengdu 610500, China) Abs tract: T he catalytic behav iors of ca tion exchange resin as catalysts on synthesizing npropy l acetate by reactive d istillation w ere stud ied. The in fluence o f the ref lux rat io, the m o le rat io o f ac id w ith a lcohol and variou s types of so lid acid cata lyst for esterification react ions w as d iscu ssed, and in tegra ting process condi t ions to screen ca talysts. The better processes cond it ions of react ion w as conf irm ed. The result o f experi m ent ind icates that the reflux rat io is 1 2, the m ole ratio o f acid to alcoho l is 1 2, and the y ield o f npro pyl acetate is 51. 49% . K ey w ords: npropy l acetate; so lid ac id ic catalyst; ca tion exchange resin; reactive distillat ion; esterifi cat ion , 1