氧化钛的介电行为.pdfVIP

L. D. ZHANG et al.: Dielectric Behaviour of Nano-Ti02 Bulks 483 phys. stat. sol. (a) 157, 483 (1996) Subject classification: 77.22; S10 Instituk o j Sold State Physics, Academia Siniea, Hefei) (u)and Department of Materials Science and Engineering, University of Science and Technology of China, Hefei2) (b) Dielectric Behaviour of Nano-Ti02 Bulks BY L. D. ZHANG (a), H. F. ZHANG (a), G. Z. WANG(a), C. M. Mo (b), and Y. ZHANG (b) (Received July 17, 1995; in revised form May 6, 1996) Two kinds of nano-Ti02 samples, including nano-anatase and nano-rutile, were prepared by the hydrothermal method and the gas condensation method, respectively. Results of dielectric measure- ments are as follows: 1. Nano-Ti02 bulk samples (anatase and rutile) exhibit much higher dielectric constant than coarse-grain samples in the low measuring frequency range. 2. For both nano-anatase and nano-rutile, one peak appears in the spectrum of dielectric constant versus temperature, and it is located in the measuring temperature range of -150 to 150 C for nano-anatase and in the meas- uring temperature range of 25 to 450 C for nano-rutile. 3. For both nano-anatase and nano-rutile, in the spectrum of dielectric loss versus temperature there exists one peak. The mechanisms of the above-mentioned phenomena were discussed in detail. 1. Introduction The dielectric behaviour is very important for dielectric materials. Up to now, reports on the dielectric behaviour of nanostructured materials are very scarce [l to 31. In this paper, we intend to investigate the c