磁核共振Assignment-1.pdfVIP

InstructionsforProblemassignment1 (readcarefully) Usingthedatafromtheattached 1HNMRspectrum(plusexpansions),fillouttheincludedform exactlyasdescribedbelow.Thereisnostructure;thusleavetheassignmentcolumnblank.For thisproblem,youwillsubmittheattachedformonly. Instructions for completing the 1H NMR DATA form for problem 1 instrument typically 500 MHz or 600 MHz solvent the molecular formula for the solvent used, i.e, CDCl , 3 CD COCD , C D , etc. 3 3 6 6 chemical shift in decending order, normally to 2 decimal places. integration 1H, 2H, 3H, etc. multiplicity For 1st order multiplet use: s (singlet), d (doublet), t (triplet), q (quartet), qn (quintet) or combinations thereof; e.g., dd, ddd, dt, dddd, ddt, etc. (note: always have d before t or q and t before q; i.e, always dt, never td). Where possible, use t and q only for situations where the relevant coupling constants must be identical (not just similar). For example, a a t arising from coupling to two different Hʼs should be assigned as a dd (with two Jʼs of simlar of the same value) or an ap t (ap is apparent) with one J value. Similarly, use ap t for apparently simple signals from AAʼXXʼ spin systems and ap q for apparently simple signals from A XY spin