微波消解ICP-AES 法测定婴幼儿配方乳粉中9 种微量元素.pdfVIP

现代食品科技 Modern Food Science and Technology 2010, Vol.26, No.2 微波消解ICP-AES法测定婴幼儿配方 乳粉中9种微量元素 杨彦丽，林立，周谙非，陈光 （国家食品质量安全监督检验中心，北京 100094） 摘要：本文采用微波消解-电感耦合等离子体原子发射光谱法( ICP-AES)同时测定了婴幼儿配方乳粉中 K、Na 、Ca、Mg 、Fe、 Mn 、Cu、Zn、P 的微量元素含量。对使用仪器的工作参数进行了最佳的优化，测定婴幼儿配方乳粉的精密度和回收率，方法的精密 度 RSD 为 1. 9%~5.3%之间，回收率为94%~110%之间。方法用于分析国家一级标准参考物质GBW 10018(鸡肉) 、GBW 10017 (奶粉) ， 被测元素测定值与标准值或参考值吻合。 关键词：微波消解；ICP-AES；婴幼儿配方乳粉；微量元素 文章篇号:1673-9078(2010)2-209-211 Determination of 9 Kinds of Trace Elements in Infant Formula Milk Powder by Inductively Coupled Plasma Optical Emission Spectrometry with Microwave Digestion Sample Preparation YANG Yan-li, LIN Li, ZHOU An-fei, CHEN Guang (China Food Quality Safety Supervision ang Inspection center, Beijing 100094, China) Abstract: The method for determination of 9 trace elements (K , Na , Ca , Mg , Fe , Mn , Cu , Zn and P) in infant formula milk powder by using microwave digestion- inductively coupled plasma optical emission spectrometry (ICP-AES) was developed. The conditions for instrumental parameters were optimized and the accuracy and coefficient of recovery were determined. Results showed that the relative standard deviation of method were within 1.9%-5.3% and recovery were of 94%-110%. The method had been applied to analyze National Standard Reference Materials GBW 10018 (chicken) , GBW 10017 (milk powder),.The results were in good agreement with the certified or reference values. Key words: microwave digestion; ICP-AES; infant formula milk powder; trace elements 婴幼儿配方乳粉又称母乳化奶粉，是人乳的代用 乳粉中的微量元素具有实际意义。 品，除了人乳之外，婴幼儿配方乳粉是婴儿营养物质的 目前，食品中的微量元素测定多采用分光光度法、 主要来源，是出生后前几个月内