游离氧化钙对水泥浆体体积膨胀的影响机制.docVIP

游离氧化钙对水泥浆体体积膨胀的影响机制 施惠生赵玉静沙丹丹同济大学无机材料科学与工程系(上海,200092) 摘 要 硬化水泥浆体由于水泥中游离氧化钙水化常会导致体积膨胀。研究发现,浆体的体积膨胀除与fCaO 的含量和活性有关外,还与浆体的结构和性能密切相关。fCaO 水化形成Ca (OH) 2 时,不仅固相体积增加,而且空隙体积亦增加。fCaO 在浆体硬化结构形成之后水化,且其水化产物成堆聚集时才会导致浆体体积膨胀。 关键词 游离氧化钙,水化,硬化水泥浆体,体积膨胀 Abstract Hydration of f ree lime of ten leads to a volumet ric expansion of hardened cement pastes . The research result sindicate t hat t his expansion corresponds not only wit h t he content and reactivity of f ree lime but also wit h t he st ruct ureand performance of hardened pastes . The formation of Ca (OH) 2 by t he hydration offree lime result s in t h