毕业设计（论文）-新型BiOBr光催化剂的合成及催化性能研究.docVIP

分类号： O643.3 2014届本科生毕业论文 题目：新型BiOBr光催化剂的合成及催化性能研究 作 者 姓 名： 学 号： 2012090710 学院 、专业： 生物与化学工程学院、化学工程与工艺 指导教师姓名： 指导教师职称： 讲师 2014 年 6 月 6 日本文以金属铋、浓硝酸、溴化钠和醋酸等为原料，利用水热法在不同的条件（不同的温度、不同反应时间）下成功的制备出了BiOBr光催化剂。利用扫描电子显微镜、X光电子能谱仪、X-射线衍射仪、红外吸收光谱、粒度分析仪等仪器并对合成催化剂进行了性质表征。结果表明所合成催化剂形貌为规则花球状团簇化合物，粒径分布均匀，80℃/2h、120℃/2h、120℃/4h、120℃/6h合成的粒径分别大概为110nm、25nm、72nm、230nm。以对苯二酚为目标污染物，研究所制备BiOBr催化剂的光催化性能，研究了不同制备条件、不同催化温度、不同催化反应时间、不同催化剂用量、有无光照等对催化性能的影响，结果表明120℃/6h制备的BiOBr光催化剂在35℃恒温下，经过紫外光照催化活性最好，降解效率达到79％。 关键词：BiOBr；光催化剂；制备；光催化性能；水热法BiOBr photocatalyst was synthesized by bismuth, concentrated nitric acid, sodium bromide and acetic acid using hydrothermal method at various temperature and different reaction time. Base on analytical method of scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, infrared absorption spectroscopy and particle size analyzers ,the catalysts were characterized. The results showed that the morphology of synthesis catalyst appeared to globular clusters and particle distribution is uniformity. The catalysts were synthesized under 80 ℃ / 2h, 120 ℃ / 2h, 120 ℃ / 4h, 120 ℃ / 6h, the particle diameters were 110nm, 25nm, 72nm, 230nm respectively. In order to study photocatalytic properties of BiOBr, target pollutants was chose to hydroquinone, catalytic performance of catalysts were studied in different preparation conditions, such as different catalytic temperature different catalytic reaction time, different amount of catalyst, and the presence or absence of light. The result indicated: BiOBr was synthesized at 120 ℃ / 6h. The catalytic activity of BiOBr was better when it was prepared at 35 ℃ under UV irradiation. The degradation efficiency was 79%. Keywords: BiOBr; Photocatalyst; Thesis; Photocatalytic properties; Hydrothermal 目 录 引言 1 1 实验部分 2 1.1 实验