TS_1_尿素_过氧化氢体系中的丙烯环氧化反应_英文_.pdfVIP

25 7 2004 7 Vol. 25 No. 7 Chinese Journal of Catalysis July 2004 Article ID: 0253-9837( 2004) 07- 05 13- 02 Communication: 513~ 5 14 Highly Effective Epoxidation of Propylene in the TS 1/ Urea/ Hydrogen Peroxide System CHENG Weiguo, WANG Xiangsheng, L I Gang, GUO Xinwen ( State K ey L aboratory of Fine Chemicals, Dep artment of Catalysis Chemistry and Engineering , Dalian University of Technology, Dalian 11 012 , Liaoning, China) Key words: titanium silicalite, u ea, hyd og en pe ox ide, p opy lene, epox idation, p opy lene oxide CLCnumber: O643 Document code: A P opylene oxide ( P O) is one of the indust ially syst em. impo t ant bulk chem icals. T he convent ional oute fo T S- 1 w as hyd ot he mally sy nt hesized acco ding the epox idat ion of p opylene uses chlo ine and lime, t o Ref [ 17] . T he at io of SiO2/ T iO2 was 4517 . T he and p oduces m uch pollution. H alcon has developed a p opylene epox idat ion w as ca ied out in a stainless comme cial p ocess f o the manufactu e of PO based steel aut oclave eacto , w hich w as im me sed in a on Ref [ 1] , but la ge amount s of side p oducts such t empe atu e-cont olled bat h at the equi ed tem pe a- as t-butyl alcohol o sty ene we e p oduced. tu e. Residual H2 O2 w as det e mined by i