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离子液体对稠油改质降粘机理探讨
摘 要:注蒸汽开采稠油时,高温水蒸汽与稠油之间发生的反应降低稠油粘度,但%,%%,%
Research on the Upgrading and Viscosity-reducing mechanism of Ionic Liquids on Heavy oil
Abstract:During exploitation of heavy oil steam injection,the viscosity of heavy oil can be reduced effectively by the aquathermolysis between high-temperature water vapor and heavy oil.However,these reactions need relatively high temperature. Generally above 200℃,the reaction conditions is very harsh.In order to get a better improvement in the quality of heavy oil at a relatively low temperature range,In this paper,the use of ionic liquids on upgrading the heavy oil to reduce its viscosity has been saide.First,the heavy oil viscosity reduction rate with different reaction time, temperature and ionic liquid concentrate on has been determinated when the ionic liquid called W and heavy oil response.Then the best reaction conditions were determined as 100℃,18h,15wt%.The best viscosity reduction rate is 41.8% under the best condition.Second,the composition between the best oil sample and original oil sample is contrasted,heavy components reduced,light components increased, saturated hydrocarbon and aromatic hydrocarbon increased by 10.05wt% and 4.35wt% each, colloid and asphaltene decreased by 4.43wt% and10.13wt% each,H/C increased, the content of sulfur reduced.Third, the mechanism of ionic liquid upgrading the heavy oil to reduce its viscosity was discussed based on experimental results and literature.Known by the conclusion,when ionic liquids and heavy oil response,heavy oil was upgraded by metal ionic on the heavy oil catalytic,reducing of the intermolecular forces in heavy oil,rolvent effect of light hydrocarbon and acid-base properties of the ionic liquids.A theoretical basis for the development of ionic liquids on upgrading heavy oil was provided.
Keywords: heavy oil; ionic liquids; upgrading; viscosity-redueing ; mechanism
目 录
1 绪论 1
1.1 研究的目的及意义 1
1.2 稠油降粘方法 1
1.3 离子液体的现状及其在石油行业中的应用 9
1.3.1 离子液体的发展现状 9
1.3.
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