化学工程与工艺毕业设计（论文）-In2O3纳米粉体的不同制备方法及其气敏性能的研究.docVIP

学号：0503224008 In2O3纳米粉体的不同制备方法及其气敏性能的研究 学院名称： 化学与环境科学学院 专业名称： 化学工程与工艺 年级班别： 2005级化工班 姓 名： 指导教师： 2009年05月 In2O3纳米粉体的不同制备方法及其气敏性能的研究 摘 要 以In(NO3)3·4.5H2O 为原料，采用室温固相合成法、溶剂热法、微乳液法、溶胶凝胶法、化学共沉淀法、均匀沉淀法等六种不同方法制备In2O3纳米粉体，并对其气敏机理进行简要分析。通过手段进行表征℃的工作温度下对100ppm Cl2气体的灵敏度高达1175，并且具有良好的选择性，响应－恢复时间短等特性。最后对In2O3纳米材料进行展望。 关键词 In2O3；纳米粉体；制备；气敏性能 Gas-sensing properties of nanostructured In2O3 powder–based sensor synthesized with different methods Abstract..This paper introduces several methods of the preparation of In2O3 nano-powder with In (NO3) 3 ? 4.5H2O as raw materials, including solid-phase synthesis at room temperature, solvothermal method, microemulsion method, sol-gel method, chemical co-precipitation method, homogeneous-precipitation method; and a brief analysis of gas-sensing mechanism was done. Its phase was analyzed by XRD. The calculation shows that particle size of In2O3 nano-powder prepared by the six methods were 9.89nm, 23.07nm, 22.69nm, 14.74nm, 9.30nm, 22.38nm. The gas-sensing properties of the materials were tested in static state. The results show that the In2O3 nano-powder has high sensitivity to Cl2. In2O3 nano-powder prepared by homogeneous-precipitation method has a high sensitivity as high as 1175 to 100ppm Cl2 at lower working temperature 110℃. The sensor based on In2O3 also has satisfactory selectivity, quickly response and short recover time. Finally, the prospect of In2O3 nano-materials was foreseen. Keywords..In2O3; nano-powder; preparation; gas-sensing properties 目 录 摘 要： I Abstract II 前 言 1 1实验部分 2 1.1试剂与仪器 2 1.2 实验方法 2 1.2.1室温固相合成法 2 1.2.2 溶剂热法 2 1.2.3 微乳液法 3 1.2.4 溶胶凝胶法 3 1.2.5化学共沉淀法 3 1.2.6 均匀沉淀法 3 2 气敏元件的制备，老化及测试 3 2.1 气敏元件的制备及老化 3 2.2 气敏元件的测试 4 3. 结果与讨论 5 3.1 样品的XRD测试 5 3.2 气敏性能的测定 6 3.2.1制备方法对元件灵敏度的影响 6 3.2.2 加热温度对元件灵敏度的影响 7 3.2.3 气体浓度对元件的灵敏度的影响 7 3.2.4 元件的选择性 8 3.3 气敏元件的响应—恢复特性 9 4 气敏机理探讨 9 5.结论与展望 11 参考文献 13 致 谢 15  前 言 随着科技的发展，工业生产中使