乙苯脱氢装置中间换热器的工况研究.pdfVIP

5·10 · 石　　油　　化　　工 1998 年第 27 卷 Study on the D iffusion of Zeolite M em branes F an S huansh i ( , , 102200) Schoo l of Chem ical Engineering U niversity of Petro leum Beijing W ang J inqu ( , , 116012) Institute of A dso rp tion and Ino rganic M em branes D alian U niversity of T echno logy D alian Abstract 　　 A tube shellm em b rane diffu sion experim en tal apparatu s w as designed and set up T he tran s po rt characteristics of the m em b rane cell w ere analyzed, and the m athem atical m odel w as , , 5 p ropo sed T he efficiency diffu sivities of w ater ethano l xylenes and ethylbenzene in ZSM zeo lite m em b ranes w ere investigated T he resu lts show that the self m ade silica and zeo lite m em b ranes have differen t diffu sion m echan ism s, the fo rm er belong to Knudsen diffu sion and the latter have som e shape selective diffu sion p roperties Keywords: ino rgan ic m em b ranes, zeo lite m em b ranes, diffu sivities, diffu sion m odel 乙苯脱氢装置中间换热器的工况研究 毛连生　朱冬茂 (上海石油化工研究院, 上海 201208) 摘要　利用PRO 软件对脱氢反应、加热及换热部分流程工况进行模拟计算。将乙苯脱氢反应的 中间换热器中的物料流向进行了比较, 发现采用顺流换热方式, 有利于抑制乙苯、苯乙烯的热裂解 副反应的发生; 而采用逆流换热方式, 换热器的设计温度可降低 35 ℃, 反应器的材质要求亦可相应 地降低。研究了两种换热流向对系统操作的影响, 确定了苯乙烯的生产装置设计时中间换热器的操 作条件。