物理化学的研究方法3.ppt

Cyclic voltammetry Nernstian (reversible) systems Peak current is linear with square root of scan rate No effects of scan rate on peak potential Reductive peak current is equal to oxidative peak current Value of peak potential difference is 58 mV/n Peak current and scan rate At 25℃, ip is Totally irreversible systems Scan rate In LSV, the potential is scanned from a lower limit to an upper limit Unit of scan rate(υ): V/s or mV/s Effects of scan rate on charging current: Differential Pulse Voltammetry/Polarography Differential Pulse Voltammetry/Polarography Sampled Current Polar