非负载加氢脱氧催化剂制备和活性评价的初步研究.pdfVIP

非负载加氢脱氧催化剂制备与活性评价的初步研究 王欣∗，侯凯湖 （河北工业大学绿色化工研究所，天津 300130） 摘要：本文对生物油加氢脱氧精制非负载型催化剂的制备及其活性评价做了初步的探索研究。采用水热分解硝酸镍 和钼酸铵的方法制备了Ni-Mo-Al O 非负载复合氧化物催化剂，初步考察了Ni-Mo-Al O 复合氧化物催化剂催化含氧 2 3 2 3 化合物组分醇、醚、酚和酸的加氢脱氧性能。结果表明Ni-Mo-Al2O3 非负载复合氧化物催化剂具有较高的低温加氢脱 氧活性，在200~250 ℃、压力0.3~0.4MPa、氢油体积比200 、液体空速2h-1 条件下，己醇、丁醇、丁醚、苯酚和乙酸 的加氢脱氧转化率可达到90% 以上。 关键词：加氢脱氧；非负载催化剂；Ni-Mo-Al O ；水热分解 2 3 Preliminarily Study on the Preparation and the Activity Evaluation of Unsupported Catalysts for Hydrodeoxygenation Wang xin, Hou kaihu (Institute of Green Chemical Technology, Hebei University of Technology, Tianjin 300130, China) Abstract ：The preparation and the activity evaluation of the unsupported catalysts for bio-oil hydrodeoxygenation were conducted in this article. Unsupported composite oxides Ni-Mo-Al O catalysts 2 3 were prepared using a hydrothermal decomposition method of nitrate hexahydrate and ammonium paramolybdate. Activity evaluation of the catalysts was carried out in a continuous fixed bed reactor. Hydrodeoxygenation performance of the catalysts for oxygenated compounds, such as hexanol, butyl ether, phenol and acetic acid was preliminarily examined. The results showed that the catalyst has excellent hydrodeoxygenation activity under mild reaction conditions. Conversions of hexanol, Butanol, butyloxide, phenol and acetic acid were over 90%, respectively, under the conditions as follows: temperature