赣南富稀土矿区农田土壤中稀土元素的环境化学特征.pdfVIP

土壤与环境 2001, 10(1): 11~ 13 Soil and Environmental Sciences E-mail: ses@ 文章编号 1008-181X 2001 01-0011-03 赣南富稀土矿区农田土壤中稀土元素的环境化学特征 高效江1 2 2 章 申 王立军 1 复旦大学环境科学与工程系 上海 2004332 中国科学院地理研究所 北京 100101 摘要 选择江西赣县大田稀土矿区 研究了矿区耕作农田土壤中稀土元素的含量 分布及赋存形态特征 结果表明 该区 土壤中稀土元素含量明显高于对照区和全国土壤平均含量 且相对富含重稀土元素 土壤中稀土元素的分布模式受成土母 岩及元素性质控制 呈现Eu 和Ce 负异常 稀土元素主要以可交换态和有机结合态 特别是松结有机态 形式存在 具有 较高的活性和生物有效性 可能影响生态环境安全 关键词 土壤 稀土元素 分布 形态 中图分类号 X131.3 文献标识码 A Environmental chemistry of rare earth elements (REEs) in the cultivated soil of a typical REE mine in the southern Jiangxi GAO Xiao-jiang 1 ZHANG Shen2 WANG Li-jun2 1: Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China; 2: Institute of Geography, Chinese Academy of Sciences, Beijing 100101, China Abstract: Content, distribution and speciation of rare earth elements (REEs) in the cultivated soils from a typical REE mine in the southern Jiangxi, were studied. Results showed that the REE contents of soils in the REE-rich area are obviously higher than that of contrast area and the average value of China soils. The normalized-distribution patterns of soils present the Eu and Ce negative anomalies, which is controlled by the parent rock and the physico-chemical properties of individual REEs. The main forms of REEs in soils are (loosely) bound to organic matters and exchangeable, so REE have higher activity and bioavailability. Key words: rare earth elements (REEs); soil; distribution; speciation 我国稀土资源丰富 随着稀土元素在工农业和 数十米的风化壳富含稀土 高新技术领域的广泛应用 环境中稀土元素的化学 2 材料与方法 行为及其对生态环境的影响也日益受到人们的关 2.1土样的采集和处理 注[1, 2] 国内外学者在稀土元素环境化学方面已作 赣县大田稀土矿区山前冲积平地为附近