《南通大学学报》论文模板.docVIP

纳米Ag/TiO2复合材料的制备及性能研究 鞠剑峰1，胡啸林2 （ 1. 南京理工大学，江苏　南京210094；2. 南通大学, 江苏 南通 226007） 摘 要：采用溶胶凝胶法制备纳米Ag/TiO2复合材料，研究其抗菌性能和光催化性能，并以X射线衍射（XRD）、透射电镜（TEM）、X射线光电子能谱（XPS）进行表征．结果表明，复合材料不需紫外光照射即具有较强的抗菌性能，对大肠杆菌和金黄葡萄球菌产生13~17 mm的透明抑菌圈．n(Ti):n(Ag)=20:1时，复合材料的抗菌性能最佳，抑菌圈达到17 mm，同时显示出较高的光催化活性．复合材料中，银以单质形式存在，形成纳米团簇富集在复合材料表面成为电子积累中心，减少光生电子和空穴的复合，抑制粒径的长大，促进复合材料从锐钛矿向金红石相的转移，从而提高复合材料的抗菌性能和光催化活性． 关键词：TiO2；纳米复合材料；银；抗菌性能；光催化性能 中图分类号：O643 文献标识码：A Preparation and Activity of Nanocomposite Ag/TiO2 Material JU Jian-feng１，HU Xiao-lin２ ( 1. Nanjing University of Science and Technology; Nanjing 2100094; 2.Nantong University, Nantong 226007,China) Abstract: Nanometer Ag/TiO2 composite materials were prepared by Sol-gel method and their antibacterial and photocatalytic activity was studied. They were characterized by XRD, TEM and XPS. Experimental results show that the composite materials have excellent antibacterial activity without UV irradiation. They have clear antibacterial circle of 13~17 mm. The antibacterial activity is best whose antibacterial circle is 17 mm and has higher photocatalytic activity at the same time when n(Ti):n(Ag) is 20:1. Element silver exist as elemental substance silver state that form nanometer silver cluster on the surface of composite material to be the accumulating center of electrons. Thus the recombination of photo-generated electrons and holes is reduced, the growth of crystal size is resisted, the change from anatase to rutile phase is accelerated, and the antibacterial activity and photocatalytic activity is enhanced. Keywords: TiO2; nanometer composite material; silver; antibacterial activity; photocatalytic activity 0 引 言 近年来半导体多相光催化氧化消除环境污染物的净化技术日益受到人们的重视，并逐渐发展成为环境污染治理技术中的一项新技术. 纳米TiO2由于价廉易得，耐腐蚀，光化学性质稳定及较强的光催化能力而备受青睐[1-2]．…… 本文采用溶胶凝胶法制备了掺杂不同质量分数Ag的纳米[3]Ag/TiO2复合材料，考察了其抗菌性能和对甲基橙的光催化降解反应，复合材料不需紫外光照射就具有较强抗菌性能，与纯TiO2相比，复合材料光催化活性大大提高，对其机理进行了初步研究． 1 实验部分 1.1 复合材料的制备 以钛酸丁酯（Ti(OC4H9)4 ）和AgNO3为主要原料，采用溶胶凝胶法制备[4]…… 1.2 抗菌实验 …… 1.3 光催化降解甲基橙实验 …… 1.4 表 征 …… 2