分析化学习题答案课件.pptVIP

分析化学习题 解（1） NH4H2PO4 MBE c = [NH3]+[NH4+] c = [H3PO4]+[H2PO4-]+[HPO42-]+[PO43-] CEB [H+]+[NH4+]= [H2PO4-]+2[HPO42-] +3[PO43-]+[OH-] PBE [H+]= [NH3]+[HPO42-]+2[PO43-] +[OH-] -[H3PO4] （2） NH4CN MBE c = [NH3] + [NH4+] c = [CN-] + [HCN] CEB [H+] + [NH4+] = [OH-] + [CN-] PBE [H+] = [NH3] + [OH-] - [HCN] 解:(1)0.10mol/LNH4CN溶液，NH4CN是弱 酸弱碱组成的盐 （3）0.10mol/L Na2S溶液