现代高分子物理学讲坐.pdf

, 610065 • • Single polymer chain • in confined geometry 1 • I. • II. • RW tail and SAW tail • III. • RW loop and SAW loop • IV. • V. 2 d confined chain 2 At surface 3 • Analytical methods • probability theory • diffusion equation • Monte Carlo • Molecular dynamics 4 • Confined RW • 1943 Chandraskhar • Kolmogorov • Feller • Tail polymer chain • Eirich, Frisch, Simha • I 5 Wu D. et al, Polymer 27,1087(1986) R c 6 Physical meaning of parameter w 7 Chain size vs probability w Chain size vs w 8 Random walk of 1000 steps Confined chain 9 Chain size for a confined chain Chain size component in confined dimension 10 Chain size for confined SAW •