粘结NdFeB磁体表面纳米TiO2-氟碳复合涂层的耐腐蚀性能.pdfVIP

工艺·技术·应用 粘结 NdFeB 磁体表面纳米 TiO /氟碳复合涂层的耐腐蚀性能 2 陈文钊，王 晨，罗朝林，李 媛 （福州大学材料科学与工程学院，福建福州 350108 ） 摘 要：将硅烷偶联剂 KH-550 改性的纳米 TiO2 颗粒与氟碳乳液混合涂覆于粘结 NdFeB 磁体表面形成复合 防蚀涂层。研究了纳米 TiO2/ 氟碳复合涂层对粘结 NdFeB 磁体耐腐蚀性能的影响，利用扫描电镜、接触角测定 仪和电化学工作站对涂层表面形貌、疏水性和耐腐蚀性进行了表征。结果表明，经过硅烷偶联剂 KH-550 改性 的纳米 TiO2 颗粒在涂层中的分散性较好，可以有效减少涂层中的微裂纹和孔洞。粘结 NdFeB 磁体表面为亲水性， 而涂刷纳米 TiO / 氟碳复合涂层后，磁体表面转变为疏水性。电化学测试表明复合疏水涂层可以有效提高磁体的 2 耐腐蚀性能。 关键词：NdFeB 粘结磁体；纳米 TiO2/ 氟碳复合涂层；耐蚀性；疏水性 中图分类号：TM273 ；TG172 文献标识码：A 文章编号：1001-3830(2015)01-0021-05 Study on corrosion resistance of bonded NdFeB magnets with nano-TiO2/fluorocarbon composite coating CHEN Wen-zhao, WANG Chen, LUO Chao-lin, LI Yuan College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China Abstract: The fluorocarbon emulsion mixed with KH550-modified TiO2 nanoparticles was coated on the surface of bonded NdFeB magnet to become anti-corrosion composite coating. The effects of nano-TiO2/fluorocarbon composite coating on the corrosion resistance of bonded NdFeB magnet were studied. The surface morphology, hydrophobicity and corrosion resistance of coating were investigated by scanning electron microscope, contact angle meter and electrochemical workstation, respectively. It is shown that the KH550-modified TiO nanoparticles disperse 2 well in the coating, and significantly reduce the micro-cracks and holes in the coating. The surface of bonded NdFeB magnet changes from hydrophilicity to hydrophobicity after brushing nano-TiO2/fluorocarbon composite coating. The electroc