锂离子电池用双草酸硼酸锂的固相合成.pdfVIP

无机盐工业 第 43卷第 4期 42 INORGANIC CHEM ICALS INDUSTRY 2011年 4月 玥, 袁 莉,刘锦平, 李晓磊, 赵 洪,宋晓莉 (, 300131) : (L iBOB) , 2. 111,, 120 240 , , ; , , : ;;; ; : TQ131. 11 : A : 1006- 4990( 2011) 04- 0042- 03 Solid phase syn thesis of L i BOB for lith ium batteries ZhangYue, Yuan L,i Liu Jinping, Li iaole,i Zhao Hong, Song iaoli ( CNOOC T ianj in Chem ical R esearch D esig n Inst itute, T ianj in 300131, Ch ina) A bstract: Synthesis of a new type lithium salt electrolyte lithium bis( oxalato) borate ( L iBOB) by solid phase meth odwas introduced in detail. In preparation process, oxalic acid, lithium hydroxide, and boric acid were used as raw materi als, whose amoun-tof- substance ratio was 2. 111. A fter m ixed by ballm illing, sintered at 120 , and dehydrated at 240 , L iBOB product could be obtained by purificationw ith ethyl acetate. Analysis results showed the producthad a com plete crystal structure and a low content of mi purities. Thermal analysis proved that its thermal stabilitywas better than that of lithium hexafluorophosphate (L iPF ). Battery assembled by LiBOB prepared electrolyte had a better cycle performance. 6 Furthermore, the prepared LiBOB reached the standard of lithium salt electrolyte used for lithium- ion batteries. K ey w ord s: lithium bis( oxalato) borate ( LiBOB); lithium- ion batteries; oxalic acid; lithium hydroxide; boric acid LiPF 6 1 , , , LiPF, 1. 1 6 H C O 2H O, 99. 5%; H BO , , , ,, , 2 2 4 2 3 3